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Are downloadable files safe?
Some store owners worry about uploading files to their site. WooCommerce uses a few different technologies to prevent users from pirating your files (https://docs.woocommerce.com/document/digital-downloadable-product-handling/).
In addition, any files you upload will be hidden from search engines.
For the most part, it isn't worth a ton of effort to prevent piracy. If a user really wants to pirate your content, they'll find a way to do so. But you can always limit downloads and add an expiry time.
One way to protect PDF is with PDF stamping (https://woocommerce.com/products/woocommerce-pdf-watermark/). This embeds personal user information in the PDF (in very small, hard-to-notice print). This way, you have some idea of who shared the original document. This PDF stamping product is a premium plugin, but there are also free solutions on the market.